I have no idea where you pulled that statement about "blends" from, but it sounds like some forum. You asked if acetone can be used to smooth PLA. It cannot. You then told me that in fact there are "blends" out there that contain ABS, apparently, and so can be vapour polished. Despite the company in question saying it is PHA they add to their PLA. PLA is not ABS.
The market for filament is becoming very competitive, and although the machines to extrude the filament are relatively large and complex, the barriers to entry are reasonably low. As a result every supplier wants people to believe their filament is the best and/or contains some magic ingredient that will differentiate it from the competition. Adding something else into a PLA filament does NOT necessarily make it a better filament than one without something added. Indeed I do know of some of these "exotic" filaments that were dreadfully out of tolerance and would often produce extrusion issues.
Your "questions" seem to be more statements where you appear to have all the answers, so I'll leave you to it then.