Some tips, a coupe of which were alluded to.
Spray the thread area with penetrating oil well in advance of when you intend to dismount the chuck.
Realize that drawtube pressure is trying to either close or open the jaws, which is helping to "lock" the threads. This is the same theory behind torquing a bolt. I turn the hyd pressure very low (so the drawtube strokes slowly), then in the rough middle of travel while closing or opening, turn the pressure to minimum, which should stop the drawtube movement. Now you have the chuck master jaws in a "neutral" position, with no load on the threads. This alone will help them unscrew.
Dig the crap out of the slots in the drawnut so the ears on the wrench will fit in full-depth. This is basic mechanics. If you don't do this, the ears are much more likely to pop out of the slots, and round everything off in the process.
Note that when you have unseated the chuck from the spindle nose, all the weight of the chuck is hanging on the end of 3.5 to 4 feet of drawtube. That short little thread at the opposite end, engaging the hydraulic cylinder, is the only thing doing all the support, and it's now taking a helluva sideload to the threads, nor is it helping the cylinder. I like to put a piece of tubing or barstock through the chuck into the drawtube at least 1.5 feet deep. Then, support the end sticking out of the chuck. This helps unload those threads at the other end. Of course, this must be done after first using the chuck wrench to unscrew several turns. At that point, the chuck body can usually be rotated to continue unscrewing the chuck off the drawtube. The tubing going through has another very beneficial use. If you do something wrong and the chuck comes off the end of the drawtube unexpectedly, it won't fall, if you have the tubing set right. I saw a guy standing inside a lathe trying to catch the chuck as it came off. It dropped, smashing his hands between the chuck and bed.
OMG, it hurt just to see. Cannot imagine how much pain that was.
Clean the chuck while it's off!!!! If you don't do it now, you'll never take it off just to clean it. Unless, of course, it quits moving. Yep, seen that one. Lots of crap gets inside, and can make so much friction that the hyd pressure can't overcome it. You'll also find a clean chuck will stroke at a much lower minimum pressure, which is great help when holding thin-wall parts. That same crap can also build up between the spindle ID and drawtube OD and cause a lot of friction. I've seen that also bring a chuck to a halt. Very often, the grease passages inside the chuck get clogged. So, you're pumping in grease, but it's not going to all the right places.
When you put it back on, use the anti-seize, as mentioned. Makes a world of difference in getting it off on the next round.
If the chuck absolutely won't come off without the drawtube unscrewing from the cylinder, so be it. Take the assembly off, clamp the drawtube in a vise (no more than necessary pressure) and you should now be able to separate them. (Try to avoid jaw marks in the drawtube, as these could be stress-risers.) Clean the cylinder-end drawtube threads really well, then screw the drawtube back in with removable Loctite on the threads. This and the anti-seize at the chuck should make it come apart properly next time. Some drawtubes have a thin-wall locknut on the threads at the cylinder end. It should do a good job at preventing the drawtube from unscrewing. Unfortunately, these locknuts aren't on all machines.
Worst-case scenario is the chuck just WON'T come off. A customer had never pulled the chuck off their 25-year old Mori. Damn, that was stuck. It took heating with a torch to persuade it. Obviously, this is an extreme measure and requires some caution and common-sense. But, it worked with no damage.
Liberal usage of profanity will not help the threads unscrew, but it might make you feel better.