Prefetch,
I second the "welding tips and tricks" reference on YouTube. Great knowledge base.
With all respect, that weld looks like something the dog ate- a day after eating it. First off, don't use pulse mode. It is great for some applications, but your settings are probably not optimum and thus you are not getting enough heat. Set the welder for 200 amps, AC mode (with foot pedal I assume), with perhaps 15CFH argon flow. Use at least a 3/32" electrode. Some people prefer to ball the electrode, and thus use a pure tungsten electrode and light up with polarity reversed on a piece of copper to melt the tip. I prefer to use a sharp tip on the tungsten, and use 1.5% gold lanthanated electrodes. I use 1/8" diameter for most aluminum welding. Be sure the electrode is ground with the grind marks axially. Keep the stickout from the ceramic cup to perhaps 1/4" unless you are using a gas lens. You do not need big stickouts for this weld.
Next, do this exercise (as suggested by Jody on Weldingtipsandtricks.com if you want his official website. Start with a piece of 1/8" aluminum sheet. Clean it with alcohol or acetone, then wire brush with a new stainless brush you will use only for aluminum. Using a 3/32" 4043 (I usually use 5356, as most of my welding is for marine applications) filler metal, and the welder set at 70% balance, AC, and 200 amps.For this application I suggest 200 Hz frequency. Use at least a 3/32" electrode in the torch, as per above. Light up on the right hand side(assuming a right handed welder)of the sheet of aluminum by moving the electrode in a 1/4" diameter circle and gradually (over about 2 seconds) increasing the current. You should see a shiny puddle appear as the reverse current (30% in this case) blasts the oxide clean and the sheet starts to melt under the electrode. Start running a bead from right to left on the sheet of aluminum. Dip the filler metal into the weld puddle about every 1/8" of torch travel. You should start seeing the famous "stack of dimes" weld bead. You will find that you have to back off on the current as you heat the sheet.
When you reach the end of the bead, back off slowly on the current while circling the torch to end the bead without cratering. Now go back to the right side of the sheet and do it all again, and again, and again, etc until it starts to feel natural. Jody suggests making pyramids and walls by stacking beads- this is great practice. Look closely at the puddle, and play around with the torch angle, speed and dipping technique to get the best result you can.
Back at the tube, make sure the tube ends are clean. Prep the weld by grinding a bevel on each side perhaps 1/2 to 2/3 through the tube wall on both ends of the tube. Using a 90 degree countersink in a mill is a lovely way to do it, but a belt sander or handheld grinder will work also. Even a file is ok. Fixture the ends of the tube so they touch with the chamfers facing each other. Use clamps or other techniques to hold everything stable. Try lighting up on a corner with the small circling technique, and when you get a good puddle, dip the rod, and then back off on the torch to make a tack weld on the corner. Go to the opposite corner and tack that. Then the other two corners. Corners may be easier to tack as the corner is less capable of conducting away the heat from the torch and therefor heat up quickly. Now check the alignment of the tubes. If you need to, break or cut the tacks and redo it to get the desired straightness. Now using the technique you practiced on the 1/8" sheet, run beads on the 4 sides of the tube. I would probably do opposite sides first, then the other two sides. At the end of it, the chamfer will have allowed good penetration. You will get very poor results if you just butt square sided edges together and try to weld them that way. Edge prep for welding is a well known science, and the proper ways of doing it can be found in many handbooks. During the welding you will need to adjust the current to compensate for the tube heating up.
Aluminum has a reputation for being hard to weld due to the oxide layer, the high thermal conductivity, and the low melting point. It is really quite fun to weld, and great results are not hard to obtain with good equipment and most importantly, LOTS OF PRACTICE. THere is no substitute for LOTS OF PRACTICE combined with lots of reading to learn the techniques that you will practice. Your welds should be shiny, clean looking, smooth edged, and have good penetration. Therre is nothing particularly magical about the "stack of dimes" look as far as I know, but if you can get them looking like a machine made them, you probably have learned some good basic technique. Sometimes preheating 200 degrees or so with a propane torch will make a thick section very weldable, as will a larger diameter tungsten, a larger tip angle on the grind, and perhaps a little helium mixed into the argon. Finally, NEVER,NEVER, NEVER keep welding after you stick the electrode in the puddle or with the filler metal and contaminate it. Just DON'T DO IT! Your welds will look and BE real crap. Take a minute, give a few curses, and go clean off the contamination and re-grind the proper point using a CLEAN wheel, or even better, a dedicated tungsten grinder. A technique I use which works well is to put the tungsten in a handheld electric drill and run it against a belt sand with a clean belt, with the electrode parallel to the length of the belt and pointing away from the belt travel. Wear safety glasses when grinding tungsten. This puts the grinding marks axially, and the drill rotation makes everything symmetrical. I have found breaking tungsten electrodes as some recommend to be nasty,and sometimes even a bit dangerous. It also has a tendency to splinter the electrode or microfracture it. Using an abrasive (diamond wheels are the best) to dress the electrode really works. I usually get the contaminant off with a belt sander, then use a dedicated diamond tungsten dresser (Sharpie based). When learning to weld aluminum, expect to dress a LOT of electrodes. It is just the Code of the West, Dingus. Getting a handful of electrodes all ready to go and changing rapidly and saving the grinding until you have run out of clean ones can speed things up a lot, and your poor welder can probably use a break to cool down anyway. One last tip- Get some thicker welding gloves, not the really thin ones you commonly see people who weld light gage steel on TV wear. Aluminum weldments get REALLY,REALLY HOT and the thin gloves will allow bad burns, where a MIG style thicker glove will protect your hands better. Also consider getting one of Jody's "TIG Fingers", a fiberglass shield you can slip over a finger on the torch hand to save it when welding on larger pieces.
Hope this helps. Just remember, if it looks lousy it IS lousy (in all likelihood).
All the best,
Michael