A couple of questions:
1. If you had to choose, what material would you use?
2. What do you think about using 7075-T6 Al for both the pinion and main bevel gear?
Thanks
SD
I generally think of 7075 Al as being pretty good for static strength, but try not to use it where there's any direct rubbing going on, and certainly not Al on Al. For most applications, identical materials rubbing is the quickest way to wear and particle generation.
For what you're doing, if we take cost out of the equation I'd be thinking something like hardened 440C or 17-4 H900 stainless for the pinion, with as close to a polished tooth face as I could get.
For the main gear, a tough, hard plastic like PEEK might work for you, ideally with a fill material like glass or carbon fiber (but you'd NEED hard metal pinions with a fill).
StackPath
Replacing Metal with PEEK Polymers to Improve Gear Reliability, Performance and Efficiency
What occurred to me after thinking about your setup (but without checking the drawings, because reasons) is you need a stable relationship between the mating gear teeth, and as you apply load to them the teeth want to separate due to wedging forces.
So you need good brackets to support the gears and keep them in proper mesh, and a stiff material (like a reinforced plastic or a metal) for the large gear.
Not that it's ideal, but in some circumstances I could even see using the periphery of a ball bearing or two on the opposite side of the main gear to keep it from flexing away, or have the gear hub designed as stiff as possible (deep ribs), but that takes space and adds weight.
[Disclaimer - I am not an engineer, but am a reasonably accomplished mechanical designer with four patents and stuff I've made in space]