A G class Acme relies on the nut floating with respect to the shaft, or otherwise having the two very well aligned and fixed. One thread can move laterally with respect to the other and cause binding when the two try to wedge together. On a C class or centralizing thread, the crests and roots have less clearance between then, so if one thread moves laterally a bit its crest makes contact with the root of the other one before any wedging can happen, hence the name centralizing, because the tighter crest and root tolerances keep one fairly closely centralized with respect to the other. Even though both could be produced to the same lead accuracy, the C will produce more accurate positioning, since the lateral wandering of the G causes axial differences in movement for a given amount of rotation due to the fact that, as they wander they're moving on an inclined plane.